Plastic Man [Patrick "Eel" O'Brian]; Woozy Winks (introduction, origin); Zambi the Soothsayer (introduction); Homer Twitchel (introduction); Captain Murphey [aka Captain Murphy]; Mr. Mire (villain, introduction)
When Woozy saves the life of Zambi the Soothsayer, little did he realize that he'd be rewarded with invulnerability and immunity to pain. To decide his course in life, he flips a coin and pursues a life of crime, soon becoming partners with Eel O'Brian. But Plas talks Woozy into turning himself in, but when he does, the Police discover that Woozy's powers prevent him from being held. So a deal is made for Woozy to help Plastic Man capture Eel O'Brian!
Phantom Lady [Sandra Knight]; Masie; Don Borden; phony Phantom Lady (villain); un-named Nazis spies (villains)
The authorities begin a search for the Phantom Lady, who was seen blowing up a neutral foreign consul building. The real Phantom Lady, however, is soon captured by the spies responsible and they intend to use her to drive to the White House so they can attack and destroy it.